Comparison of fire classes
American |
European |
Australasian |
Fuel/Heat source |
Class A |
Class A |
Class A |
Ordinary combustibles |
Class B |
Class B |
Class B |
Flammable liquids |
Class C |
Class C |
Flammable gases |
Class C |
- |
Class E |
Electrical equipment |
Class D |
Class D |
Class D |
Combustible metals |
Class K |
Class F |
Class F |
Cooking oil or fat |
Ordinary combustibles
"Ordinary combustible" fires are the most common type of fire, and are designated Class A under both systems. These occur when a solid, organic material such as wood, cloth, rubber, or some plastics[1] become heated to their ignition point. At this point the material undergoes combustion and will continue burning as long as the four components of the fire tetrahedron (heat, fuel, oxygen, and the sustaining chemical reaction) are available.
This class of fire is commonly used in controlled circumstances, such as a campfire, match or wood-burning stove.
To use the campfire as an example, it has a fire tetrahedron—the heat
is provided by another fire (such as a match or lighter), the fuel is
the wood,
the oxygen is naturally available in the open-air environment of a
forest, and the chemical reaction links the three other facets. This
fire is not dangerous, because the fire is contained to the wood alone
and is usually isolated from other flammable materials, for example by
bare ground and rocks. However, when a class-A fire burns in a
less-restricted environment the fire can quickly grow out of control and
become a wildfire. This is the case when firefighting and fire control techniques are required.
This class of fire is fairly simple to fight and contain—by simply
removing the heat, oxygen, or fuel, or by suppressing the underlying
chemical reaction, the fire tetrahedron collapses and the fire dies out.
The most common way to do this is by removing heat by spraying the
burning material with water; oxygen can be removed by smothering the fire with foam from a fire extinguisher; forest fires are often fought by removing fuel by backburning; and an ammonium phosphate dry chemical powder fire extinguisher (but not sodium bicarbonate or potassium bicarbonate both of which are rated for B-class[2] fires) breaks the fire's underlying chemical reaction.
As these fires are the most commonly encountered, most fire departments
have equipment to handle them specifically. While this is acceptable
for most ordinary conditions, most firefighters find themselves having
to call for special equipment such as foam in the case of other fire.
Flammable liquid and gas
A CO2 fire extinguisher rated for flammable liquids and gasses
These are fires whose fuel is flammable or combustible liquid or gas.
The US system designates all such fires "Class B". In the
European/Australian system, flammable liquids are designated "Class B",
while burning gases are separately designated "Class C". These fires
follow the same basic fire tetrahedron (heat, fuel, oxygen, chemical
reaction) as ordinary combustible fires, except that the fuel in
question is a flammable liquid such as gasoline, or gas such as natural gas.
A solid stream of water should never be used to extinguish this type
because it can cause the fuel to scatter, spreading the flames. The most
effective way to extinguish a liquid or gas fueled fire is by
inhibiting the chemical chain reaction of the fire, which is done by dry
chemical and Halon extinguishing agents, although smothering with CO2
or, for liquids, foam is also effective. Halon has fallen out of favor
in recent times because it is an ozone-depleting material; the Montreal
Protocol declares that Halon should no longer be used. Chemicals such as
FM-200 are now the recommended halogenated suppressant.
Electrical
Electrical fires are fires involving potentially energized electrical
equipment. The US system designates these "Class C"; the Australian
system designates them "Class E". This sort of fire may be caused by
short-circuiting machinery or overloaded electrical cables. These fires
can be a severe hazard to firefighters using water or other conductive
agents: Electricity may be conducted from the fire, through water, the
firefighter's body, and then earth. Electrical shocks have caused many firefighter deaths.
Electrical fire may be fought in the same way as an ordinary
combustible fire, but water, foam, and other conductive agents are not
to be used. While the fire is or possibly could be electrically
energized, it can be fought with any extinguishing agent rated for
electrical fire. Carbon dioxide CO2, FM-200 and dry chemical powder extinguishers such as PKP
and even baking soda are especially suited to extinguishing this sort
of fire. PKP should be a last resort solution to extinguishing the fire
due to its corrosive tendencies. Once electricity is shut off to the
equipment involved, it will generally become an ordinary combustible
fire.
In Europe "Electrical Fires" are no longer a class of fire as
electricity can not burn. The items around the electrical sources may
burn. By turning the electrical source off, the fire can be fought by
one of the other class of fire extinguishers.
Metal
Certain metals are flammable or combustible. Fires involving such are
designated "Class D" in both systems. Examples of such metals include sodium, titanium, magnesium, potassium, uranium, lithium, plutonium, and calcium.
Magnesium and titanium fires are common. When one of these combustible
metals ignites, it can easily and rapidly spread to surrounding ordinary
combustible materials.
With the exception of the metals that burn in contact with air or
water (for example, sodium), masses of combustible metals do not
represent unusual fire risks because they have the ability to conduct
heat away from hot spots so efficiently that the heat of combustion
cannot be maintained—this means that it will require a lot of heat to
ignite a mass of combustible metal. Generally, metal fire risks exist
when sawdust, machine shavings and other metal 'fines' are present.
Generally, these fires can be ignited by the same types of ignition
sources that would start other common fires.
Water and other common firefighting materials can excite metal fires
and make them worse. The NFPA recommends that metal fires be fought with
"dry powder" extinguishing agents. Dry powder agents work by smothering
and heat absorption. The most common of these agents are sodium chloride granules and graphite powder. In recent years powdered copper has also come into use.
Some extinguishers are labeled as containing dry chemical extinguishing agents. This may be confused with dry powder.
The two are not the same. Using one of these extinguishers in error, in
place of dry powder, can be ineffective or actually increase the
intensity of a metal fire.
Metal fires represent a unique hazard because people are often not
aware of the characteristics of these fires and are not properly
prepared to fight them. Therefore, even a small metal fire can spread
and become a larger fire in the surrounding ordinary combustible
materials.
Cooking oils and fats (kitchen fires)
Fires that involve cooking oils
or fats are designated "Class K" under the American system, and "Class
F" under the European/Australasian systems. Though such fires are
technically a subclass of the flammable liquid/gas class, the special
characteristics of these types of fires, namely the higher flash point,
are considered important enough to recognize separately. Saponification
can be used to extinguish such fires, as can dry-powder, CO2 or, for
small fires, mechanical smothering. Appropriate fire extinguishers may
also have hoods over them that help extinguish the fire.